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Searching for corannulene with ALMA: observations of the Red Rectangle Nebula
Elise Koo, Alessandra Candian, Michiel Hogerheijde, Lizette Guzman-Ramirez, Javier Alcolea, Valentin Bujarrabal, Jan Cami, Pierre Cox and Peter J Sarre Monthly Notices of the Royal Astronomical Society 544(4) 4234 (2025) https://doi.org/10.1093/mnras/staf1967
Unconventional pathway for the gas-phase formation of 14π-PAHs via self-reaction of the resonantly stabilized radical fulvenallenyl (C7H5˙)
Wang Li, Mengqi Wu, Changyang Wang, Jiabin Huang, Jiuzhong Yang, Minggao Xu, Feng Zhang, Tao Yang and Long Zhao Chemical Science 16(18) 7864 (2025) https://doi.org/10.1039/D5SC00160A
Less-Dominant Resonance Configuration of Propargyl Radical Leads to a Growth Mechanism for Polycyclic Aromatic Hydrocarbons that Preserves the Cyclopenta Ring
Jinyang Zhang, Jiao Gao, Hong Wang, Jiwen Guan, Guangxian Xu, Lili Xing, Donald G. Truhlar and Zhandong Wang Journal of the American Chemical Society 147(11) 9283 (2025) https://doi.org/10.1021/jacs.4c15155
Analysis of the 3.2–3.3 μm Interstellar Absorption Feature on Three Milky Way Sightlines
Combining synchrotron vacuum-ultraviolet photoionization mass spectrometry and gas chromatography–mass spectrometry for isomer-specific mechanistic analysis with application to the benzyl self-reaction
Guangxian Xu, Hong Wang, Jinyang Zhang, Jiao Gao, Jiwen Guan, Qiang Xu, Donald G. Truhlar and Zhandong Wang Nature Communications 15(1) (2024) https://doi.org/10.1038/s41467-024-53889-9
Electronic Spectrum of α-Hydrofulvenyl Radical (C6H7), and a Simple and Accurate Recipe for Predicting Adiabatic Ionization Energies of Resonance-Stabilized Hydrocarbon Radicals
Jonathan Flores, Massimo Ruscitti, Sima Khani and Neil J. Reilly The Journal of Physical Chemistry A 128(38) 8123 (2024) https://doi.org/10.1021/acs.jpca.4c04746
Fulvenallenyl Radical (C7H5·)-Mediated Gas-Phase Synthesis of Bicyclic Aromatic C10H8 Isomers: Can Fulvenallenyl Efficiently React with Closed-Shell Hydrocarbons?
Alexander M. Mebel, Wang Li, Luna Pratali Maffei, Carlo Cavallotti, Alexander N. Morozov, Chang-Yang Wang, Jiu-Zhong Yang, Long Zhao and Ralf I. Kaiser The Journal of Physical Chemistry A 128(28) 5707 (2024) https://doi.org/10.1021/acs.jpca.4c02386
Role of Acetylene in the Chemical Evolution of Carbon Complexity
A combined experimental and computational study on the reaction dynamics of the 1-propynyl (CH
3
CC, X
2
A
1
) – propylene (CH
3
CHCH
2
, X
1
A′) system: formation of 1,3-dimethylvinylacetylene (CH
3
CCCHCHCH
3
, X
1
A′) under single collision conditions
Iakov A. Medvedkov, Anatoliy A. Nikolayev, Chao He, Zhenghai Yang, Alexander M. Mebel and Ralf I. Kaiser Molecular Physics 122(7-8) (2024) https://doi.org/10.1080/00268976.2023.2234509
Influences on Infrared Spectra of Benzene Ices for Titan, Comets, and Beyond: Annealings, Artifacts, and Isosbestic Points
A unified reaction network on the formation of five-membered ringed polycyclic aromatic hydrocarbons (PAHs) and their role in ring expansion processes through radical–radical reactions
Gas-phase preparation of azulene (C10H8) and naphthalene (C10H8) via the reaction of the resonantly stabilized fulvenallenyl (C7H5˙) and propargyl (C3H3˙) radicals
Wang Li, Jiuzhong Yang, Long Zhao, David Couch, Myrsini San Marchi, Nils Hansen, Alexander N. Morozov, Alexander M. Mebel and Ralf I. Kaiser Chemical Science 14(36) 9795 (2023) https://doi.org/10.1039/D3SC03231K
Fragmentation of the PAH cations of Isoviolanthrene and Dicoronylene: A case made for interstellar cyclo[n]carbons as products of universal fragmentation processes
Helgi Rafn Hrodmarsson, Jordy Bouwman, Alexander G.G.M. Tielens and Harold Linnartz International Journal of Mass Spectrometry 485 116996 (2023) https://doi.org/10.1016/j.ijms.2022.116996
Adsorption of Polycyclic Aromatic Hydrocarbons and C60 onto Forsterite: C–H Bond Activation by the Schottky Vacancy
Product Detection of the CH(X2Π) Radical Reaction with Cyclopentadiene: A Novel Route to Benzene
Kacee L. Caster, Talitha M. Selby, David L. Osborn, Sebastien D. Le Picard and Fabien Goulay The Journal of Physical Chemistry A 125(32) 6927 (2021) https://doi.org/10.1021/acs.jpca.1c03517
Lyα Irradiation of Superhydrogenated Coronene Films: Implications for H2 Formation
Low-temperature gas-phase formation of indene in the interstellar medium
Srinivas Doddipatla, Galiya R. Galimova, Hongji Wei, Aaron M. Thomas, Chao He, Zhenghai Yang, Alexander N. Morozov, Christopher N. Shingledecker, Alexander M. Mebel and Ralf I. Kaiser Science Advances 7(1) (2021) https://doi.org/10.1126/sciadv.abd4044
Interaction of Aromatic Molecules with Forsterite: Accuracy of the Periodic DFT-D4 Method
Electronic Spectroscopy of cis- and trans-meta-Vinylbenzyl Radicals
Sederra D. Ross, Jonathan Flores, Daniel M. Hewett and Neil J. Reilly The Journal of Physical Chemistry A 125(29) 6420 (2021) https://doi.org/10.1021/acs.jpca.1c04496
Optical Identification of the Resonance-Stabilized para-Ethynylbenzyl Radical
Sederra D. Ross, Jonathan Flores, Sima Khani, Daniel M. Hewett and Neil J. Reilly The Journal of Physical Chemistry A 125(41) 9115 (2021) https://doi.org/10.1021/acs.jpca.1c07039
Do defects in PAHs promote catalytic activity in space? Stone–Wales pyrene as a test case
Gas-Phase Optical Detection of 3-Ethynylcyclopentenyl: A Resonance-Stabilized C7H7 Radical with an Embedded 1-Vinylpropargyl Chromophore
Neil J. Reilly, Damian L. Kokkin, Meredith L. Ward, et al. Journal of the American Chemical Society 142(23) 10400 (2020) https://doi.org/10.1021/jacs.0c01579
Modeling Rotational Disruption of Grains and Microwave Emission from Spinning Dust in AGB Envelopes
Le Ngoc Tram, Thiem Hoang, Archana Soam, Pierre Lesaffre and William T. Reach The Astrophysical Journal 893(2) 138 (2020) https://doi.org/10.3847/1538-4357/ab7b5e
Examining the Class B to A Shift of the 7.7 μm PAH Band with the NASA Ames PAH IR Spectroscopic Database
Isomer-specific vibronic structure of the 9-, 1-, and 2-anthracenyl radicals via slow photoelectron velocity-map imaging
Marissa L. Weichman, Jessalyn A. DeVine, Daniel S. Levine, Jongjin B. Kim and Daniel M. Neumark Proceedings of the National Academy of Sciences 113(7) 1698 (2016) https://doi.org/10.1073/pnas.1520862113
Laboratory astrochemistry: catalytic conversion of acetylene to polycyclic aromatic hydrocarbons over SiC grains
Tao Yang, Tyler P. Troy, Bo Xu, Oleg Kostko, Musahid Ahmed, Alexander M. Mebel and Ralf I. Kaiser Angewandte Chemie International Edition 55(48) 14983 (2016) https://doi.org/10.1002/anie.201607509
Hydrogen‐Abstraction/Acetylene‐Addition Exposed
Tao Yang, Tyler P. Troy, Bo Xu, Oleg Kostko, Musahid Ahmed, Alexander M. Mebel and Ralf I. Kaiser Angewandte Chemie 128(48) 15207 (2016) https://doi.org/10.1002/ange.201607509
INSIGHTS INTO HYDROCARBON CHAIN AND AROMATIC RING FORMATION IN THE INTERSTELLAR MEDIUM: COMPUTATIONAL STUDY OF THE ISOMERS OF ${{\rm{C}}}_{4}{{{\rm{H}}}_{3}}^{+}$ ${{\rm{C}}}_{6}{{{\rm{H}}}_{3}}^{+}$ AND ${{\rm{C}}}_{6}{{{\rm{H}}}_{5}}^{+}$ AND THEIR FORMATION PATHWAYS
Quantum tunneling observed without its characteristic large kinetic isotope effects
Tetsuya Hama, Hirokazu Ueta, Akira Kouchi and Naoki Watanabe Proceedings of the National Academy of Sciences 112(24) 7438 (2015) https://doi.org/10.1073/pnas.1501328112
On the formation of pyridine in the interstellar medium
Dorian S. N. Parker, Ralf I. Kaiser, Oleg Kostko, et al. Physical Chemistry Chemical Physics 17(47) 32000 (2015) https://doi.org/10.1039/C5CP02960K
Reaction Dynamics in Astrochemistry: Low-Temperature Pathways to Polycyclic Aromatic Hydrocarbons in the Interstellar Medium
Understanding the chemical dynamics of the reactions of dicarbon with 1-butyne, 2-butyne, and 1,2-butadiene – toward the formation of resonantly stabilized free radicals
Dorian S. N. Parker, Surajit Maity, Beni B. Dangi, et al. Phys. Chem. Chem. Phys. 16(24) 12150 (2014) https://doi.org/10.1039/C4CP00639A
Understanding the chemical dynamics of the reactions of dicarbon with 1-butyne, 2-butyne, and 1,2-butadiene – toward the formation of resonantly stabilized free radicals
Dorian S. N. Parker, Surajit Maity, Beni B. Dangi, Ralf I. Kaiser, Alexander Landera and Alexander M. Mebel Phys. Chem. Chem. Phys. 16(24) 12150 (2014) https://doi.org/10.1039/c4cp00639a
Formation of 6-Methyl-1,4-dihydronaphthalene in the Reaction of the p-Tolyl Radical with 1,3-Butadiene under Single-Collision Conditions
Dorian S. N. Parker, Beni B. Dangi, Ralf. I. Kaiser, et al. The Journal of Physical Chemistry A 118(51) 12111 (2014) https://doi.org/10.1021/jp509990u
Electron angular distributions and attachment rates in o-Benzyne and Phenyl aromatic molecules: the effect of the permanent dipoles
Catalytic conversion of acetylene to polycyclic aromatic hydrocarbons over particles of pyroxene and alumina
M. Tian, B. S. Liu, M. Hammonds, et al. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 371(1994) 20110590 (2013) https://doi.org/10.1098/rsta.2011.0590
LABORATORY INVESTIGATIONS OF POLYCYCLIC AROMATIC HYDROCARBON FORMATION AND DESTRUCTION IN THE CIRCUMSTELLAR OUTFLOWS OF CARBON STARS
Crossed beam reactions of methylidyne [CH(X2Π)] with D2-acetylene [C2D2(X1Σg+)] and of D1-methylidyne [CD(X2Π)] with acetylene [C2H2(X1Σg+)]
Ralf I. Kaiser, Xibin Gu, Fangtong Zhang and Pavlo Maksyutenko Phys. Chem. Chem. Phys. 14(2) 575 (2012) https://doi.org/10.1039/C1CP22635E
Phenylpropargyl Radicals and Their Dimerization Products: An IR/UV Double Resonance Study
Kathrin H. Fischer, Jörg Herterich, Ingo Fischer, Sander Jaeqx and Anouk M. Rijs The Journal of Physical Chemistry A 116(33) 8515 (2012) https://doi.org/10.1021/jp306075a
Crossed beam reactions of methylidyne [CH(X2Π)] with D2-acetylene [C2D2(X1Σg+)] and of D1-methylidyne [CD(X2Π)] with acetylene [C2H2(X1Σg+)]
Ralf I. Kaiser, Xibin Gu, Fangtong Zhang and Pavlo Maksyutenko Phys. Chem. Chem. Phys. 14(2) 575 (2012) https://doi.org/10.1039/c1cp22635e
Low temperature formation of naphthalene and its role in the synthesis of PAHs (Polycyclic Aromatic Hydrocarbons) in the interstellar medium
Dorian S. N. Parker, Fangtong Zhang, Y. Seol Kim, et al. Proceedings of the National Academy of Sciences 109(1) 53 (2012) https://doi.org/10.1073/pnas.1113827108
Theoretical infrared spectra of biphenyl, terphenyls and tetraphenyls for astrophysical purposes